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Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks

  • Book
  • © 2017

Overview

Authors:
  1. Basudev Sahoo

    1. Angewandte Homogenkatalyse, LIKAT Rostock, Rostock,, Germany

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  • Nominated as an outstanding PhD thesis by the Westfalische Wilhelms-Universitat Munster
  • Provides an overview of selected recent advancements in emerging visible light photocatalysis and also Metal-Organic Frameworks (MOF)
  • Chapters demonstrate the results achieved with suitable introduction, strong research background and summary
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (6 chapters)

  1. Front Matter

    Pages i-xxiii
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  2. Introduction to Photocatalysis

    • Basudev Sahoo
    Pages 1-23

  3. Dual Gold and Visible Light Photoredox-Catalyzed Heteroarylations of Non-activated Alkenes

    • Basudev Sahoo
    Pages 25-57

  4. Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement

    • Basudev Sahoo
    Pages 59-80

  5. Transition Metal Free Visible Light-Mediated Synthesis of Polycyclic Indolizines

    • Basudev Sahoo
    Pages 81-107

  6. Synthesis and Characterizations of Novel Metal-Organic Frameworks (MOFs)

    • Basudev Sahoo
    Pages 109-126

  7. Experimental Section

    • Basudev Sahoo
    Pages 127-253

  8. Back Matter

    Pages 255-258
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Keywords

About this book

This unique thesis discusses the development of conceptually novel and synthetically valuable methods that use visible light photocatalysis. Each chapter addresses a different topic in the emerging field of photocatalysis, which has become an indispensable tool for organic synthesis. Photocatalysis employs environmentally harmless and abundant visible light in the presence of a photosensitizer, and as such offers an attractive alternative to harmful UV light in photo-mediated reactions. This book introduces the novel concept of merging gold catalysis with visible light photocatalysis in a dual catalytic fashion, which demonstrates their compatibility with each other for first time and has inspired the development of various reactions. Moreover, a novel trifluoromethylation method, which combines radical addition chemistry with a polar rearrangement to synthesize valuable fluorinated compounds, is presented, since compounds featuring fluorinated functionality are the subject ofincreasing attention in pharmaceutical, agrochemical and material research. It also develops an external photocatalyst-free photochemical method for the synthesis of valuable indolizine heterocycles, where the product mediates its own formation. Lastly, it describes the synthesis and characterization of two novel highly porous metal-organic frameworks (MOFs). The comprehensive text is rounded out with illustrations and color figures.



Authors and Affiliations

  • Angewandte Homogenkatalyse, LIKAT Rostock, Rostock,, Germany

    Basudev Sahoo

About the author

Basudev Sahoo studied his bachelor degree in chemistry at the Ramakrishna Mission Residential College, Narendrapur, University of Calcutta, Kolkata, India in 2009. Then he joined Indian Institute of Technology (IIT) Kanpur, India for his master studies in chemistry. After obtaining his master degree in 2011, he moved to Germany with a scholarship from International NRW Graduate School of Chemistry, Münster. He joined the group of Frank Glorius at the Westfälische Wilhelms-Universität (WWU) Münster for his PhD studies. Currently, he is a postdoctoral fellow in the group of Matthias Beller at the Leibniz-Institut für Katalyse e.V. an der Universität Rostock (LIKAT Rostock), Rostock, Germany.

Bibliographic Information

  • Book Title: Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks

  • Authors: Basudev Sahoo

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-3-319-48350-4

  • Publisher: Springer Cham

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer International Publishing AG 2017

  • Hardcover ISBN: 978-3-319-48349-8Published: 16 December 2016

  • Softcover ISBN: 978-3-319-83918-9Published: 05 July 2018

  • eBook ISBN: 978-3-319-48350-4Published: 25 November 2016

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XXIII, 258

  • Number of Illustrations: 76 b/w illustrations, 37 illustrations in colour

  • Topics: Organic Chemistry, Catalysis, Industrial Chemistry/Chemical Engineering

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